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2016:30 Measurement of Parameter Values for Predicting Corrosion Phenomena on Copper in Swedish HLNW Repositories
Passivity breakdown and pitting on pure copper, the assumed material for the canisters for the isolation of high-level nuclear waste in Sweden, has been studied in simulated, sulphide- and chloride containing granitic rock groundwater and the data are interpreted in terms of the Point Defect Model (PDM). The results indicated that a sulphide barrier layer forms on the copper surface, and that...
Content type: Publications -
2013:07 Corrosion of copper in distilled water without molecular oxygen and the detection of produced hydrogen
In this report, results are presented for copper which has been exposed to pure anoxic water in the temperature interval of 21 °C to 55 °C up to a total of 19 000 hours. Characterisations of copper surfaces after exposure have been performed ex-situ, meaning after termination of the experiment and exposing the specimen to normal atmospheric environment. Ideally characterisation of surfaces...
Content type: Publications -
2014:30 Modelling Approaches to C-14 in Soil-Plant Systems and in Aquatic Environments
Substantial expertise on carbon biogeochemistry already exists in the fields of plant physiology and aquatic ecology and therefore is it beneficial to draw on this to identify the important issues. A paper describing the BIOPROTA C-14 model inter-comparisons, and plans for the forward programme was published in Radiocarbon Journal. Further studies on C-14 (including modelling, model...
Content type: Publications -
2012:11 Issues in the corrosion of copper in a Swedish high level nuclear waste repository
The objective with this research project was to increase knowledge in the area of copper corrosion in the planned repository environment and obtain information on how copper corrosion evolves during the assessment period of 100 000 years. The equilibrium chemical composition of groundwater close to the canister as a function of temperature has been calculated by use of a thermodynamics code...
Content type: Publications -
2011:12 Analysis of Barrier Performance: Modelling of Copper corrosion scenarios with and without buffer erosion
The purpose of this project was to develop a numerical modelling capacity to address the corrosion of the copper canister under gradually changing transport conditions caused by buffer erosion and removal of buffer mass. Due to the complexity of this task, such a model cannot be realistic in all respects, but the present effort should address the feasibility of solving numerical and...
Content type: Publications -
2011:11 Handling Interfaces and Time-varying Properties in Radionuclide Transport Models
Quintessa’s QPAC code has been used to investigate the Qeq approach. The conclusions from this simulation study are the following. The basic approach to calculating Qeq values is sound, however, narrow channels could lead to the same release as larger fractures with the same pore velocity, so a channel enhancement factor of √10 should be considered. A spalling zone that increases the area of...
Content type: Publications -
2006:36 Mechanical Integrity of Canisters Using a Fracture Mechanics Approach
This report presents the methods and results of a research project for Swedish Nuclear Power Inspectorate (SKI) about numerical modeling of mechanical integrity of cast-iron canisters for the final disposal of spent nuclear fuel in Sweden, using combined boundary element (BEM) and finite element (FEM) methods The objectives of the project are: 1) to investigate the possibility of initiation...
Content type: Publications -
2007:17 Spent Fuel Dissolution and Source Term Modelling in Safety Assessment
SKI is preparing to review the license applications being developed by the Swedish Nuclear Fuel and Waste Management Company (SKB) for a final repository for the geological disposal of spent nuclear fuel (SFL-2) in the year 2009. As part of its preparation, SKI is conducting a series of technical workshops on key aspects of the Engineered Barrier System (EBS) and spent fuel. This workshop...
Content type: Publications -
2007:12 Development of a constitutive model for the plastic deformation and creep of copper and its use in the estimate of the creep life of the copper canister
The copper-iron canister for disposal of nuclear waste in the Swedish Programme has a design life exceeding 100,000 years. Whilst the operating temperature and operating stress are modest, the very long design life does require that the likely creep performance of the canister should be investigated. Many studies have been carried out by SKB but these have all involved very short duration...
Content type: Publications -
2007:19 An Applied Study of Implementation of the Advanced Decommissioning Costing Methodology for Intermediate Storage Facility for Spent Fuel in Studsvik, Sweden with special emphasis to the application of the Omega code
The aim of this applied study has been to describe in a systematic way an appropriate methodological sequence for cost estimation of crucial parameters in decontamination and decommission processes. The work has been limited to older nuclear installations and facilities. Furthermore, it may be envisaged that the process of estimating the parameters of decommissioning is one of the main issues...
Content type: Publications